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Phenylmagnesium bromide, 3M in ether, Thermo Scientific Chemicals Product Code.: 15472967
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Phenylmagnesium bromide, 3M in ether, Thermo Scientific Chemicals

Product Code. 15472967
100 mL
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Quantity:
100 mL
500 mL
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Product Code. 15472967

Brand: Thermo Scientific Alfa Aesar 087326.AE

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Description

Grignard reagent

Grignard reagent Phenylmagnesium bromide is an important reagent called as Grignard reagent used in the synthesis of organic and oraganometallic reactions. It is used to prepare phenyl aryl sulphides, sulphoxides, and sulphones. It acts as a strong acid and Lewis acid and undergoes addition reaction with many unsaturated functional groups. It is involved in the synthesis of end-functionalized regioregular poly(3-alkylthiophene)s, 1,3,3-trimethyl-6-phenyl-2-oxabicyclo[2.2.2]octan-6-ol, o-substituted benzophenones and 6-benzyl-1,3,3-trimethyl-2-oxabicyclo[2.2.2]octan-6-ol. In addition to this, it is used for the monalkylation of primary amines to get secondary amines.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 100-58-3
Molecular Formula C6H5BrMg
Molecular Weight (g/mol) 181.32
MDL Number MFCD00000038
InChI Key ANRQGKOBLBYXFM-UHFFFAOYSA-M
Synonym phenylmagnesium bromide, bromophenylmagnesium, magnesium, bromophenyl, phmgbr, phenylmagnesiumbromide, bromo phenyl magnesium, phenyl magnesium bromide, phenylmagnesium bromide solution, 3.0 m in diethyl ether, bromomagnesiobenzene, phenyhnagnesium bromide, grignard reagentShow MoreShow Less
PubChem CID 66852
SMILES Br[Mg]C1=CC=CC=C1

Specifications

Color Yellow to Brown
Density 1.14 g/mL
Odor Ether-like
Quantity 100 mL
UN Number UN3399
Sensitivity Air, light, and moisture sensitive; May form a Precipitate
Solubility Information Miscible with terahydrofuran.
IUPAC Name bromo(phenyl)magnesium
Formula Weight 181.31
Concentration or Composition (by Analyte or Components) 3M in ether
Physical Form Liquid
Chemical Name or Material Phenylmagnesium bromide
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5 results found
Lot Number Certificate Type Date Catalog Number
Lot NumberY12K047 Certificate TypeCertificate of Analysis Date27/01/2025 Catalog Number087326.AE,087326.AP
Lot NumberQ05K043 Certificate TypeCertificate of Analysis Date12/04/2024 Catalog Number087326.AE,087326.AP
Lot NumberZ15I022 Certificate TypeCertificate of Analysis Date05/01/2023 Catalog Number087326.AE,087326.AP
Lot NumberP22I042 Certificate TypeCertificate of Analysis Date22/07/2022 Catalog Number087326.AE,087326.AP
Lot NumberX30G001 Certificate TypeCertificate of Analysis Date12/04/2022 Catalog Number087326.AE,087326.AP

Safety and Handling

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Product Identifier
  • Phenylmagnesium bromide, 3M in ether
 Signal Word
  • Danger
 Hazard Category
  • Serious eye damage/eye irritation Category 1
  • Flammable liquid Category 1
  • Skin corrosion/irritation Category 1 B
  • Specific target organ toxicity Category 3
 Hazard Statement
  • H224-Extremely flammable liquid and vapour.
  • H314-Causes severe skin burns and eye damage.
  • H318-Causes serious eye damage.
  • H336-May cause drowsiness or dizziness.
  • EUH019-May form explosive peroxides.
  • EUH066-Repeated exposure may cause skin dryness or cracking.
 Precautionary Statement
  • P210-Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
  • P280-Wear protective gloves/protective clothing/eye protection/face protection.
  • P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
  • P303+P361+P353-IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.
  • P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
  • P310-Immediately call a POISON CENTER/doctor/.
 Supplemental information
  • MIXTURE LIST-Contains : Ethyl ether, Phenylmagnesium bromide
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RUO – Research Use Only

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