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Chloro(1,5-cyclooctadiene)iridium(I) dimer, Ir 57.2%, Thermo Scientific Chemicals Product Code.: 11307537
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Chloro(1,5-cyclooctadiene)iridium(I) dimer, Ir 57.2%, Thermo Scientific Chemicals

Product Code. 11307537
1 g
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0.25 g
1 g
5 g
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Product Code. 11307537

Brand: Thermo Scientific Alfa Aesar 012749.03

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Description

Chloro(1,5-cyclooctadiene)iridium(I) dimer is widely used as a precursor to other iridium complexes, which finds application in homogeneous catalysis like carbonylation, hydrosilylation, hydrofomylation, asymmetric allylic substitutions, metathesis and chiral catalysis reactions. It is involved in the preparation of Crabtree's catalyst, which is used for hydrogenation and hydrogen-transfer reactions.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

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Chemical Identifiers

CAS 12112-67-3
Molecular Formula C16H24Cl2Ir2
Molecular Weight (g/mol) 671.70
MDL Number MFCD00012414
InChI Key ZFOUDQNHNLDNLD-MIXQCLKLSA-L
Synonym chloro 1,5-cyclooctadiene iridium i dimer, bis 1,5-cyclooctadiene diiridium i dichloride, 1z,5z-cycloocta-1,5-diene; iridium; dichloride, iridium, di-.mu.-chlorobis 1,2,5,6-.eta.-1,5-cyclooctadiene di, ir2cl2 cod 2, chloro-1,5-cyclooctadiene iridium i dimer, 1z,5z-cycloocta-1,5-diene; iridium 1+Show MoreShow Less
PubChem CID 6436381
IUPAC Name (1Z,5Z)-cycloocta-1,5-diene;iridium;dichloride
SMILES [Cl-].[Cl-].[Ir+].[Ir+].C1C\C=C/CC\C=C/1.C1C\C=C/CC\C=C/1

Specifications

Melting Point 190°C (decomposition)
Color White
Odor Odorless
Quantity 1 g
Solubility Information Soluble in chloroform and toluene. Slightly soluble in acetone and alcohol. Insoluble in water.
Formula Weight 671.71
Physical Form Crystalline Powder
Chemical Name or Material Chloro(1, 5-cyclooctadiene)iridium(I) dimer

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Lot Number Certificate Type Date Catalog Number
Lot NumberX25E029 Certificate TypeCertificate of Analysis Date02/08/2024 Catalog Number012749.03,012749.01,012749.06
Lot NumberS06K018 Certificate TypeCertificate of Analysis Date18/06/2024 Catalog Number012749.03,012749.01,012749.06
Lot NumberY28J010 Certificate TypeCertificate of Analysis Date04/01/2024 Catalog Number012749.03,012749.01,012749.06
Lot NumberU09J027 Certificate TypeCertificate of Analysis Date16/08/2023 Catalog Number012749.03,012749.01,012749.06
Lot NumberY16I029 Certificate TypeCertificate of Analysis Date11/01/2023 Catalog Number012749.03,012749.01,012749.06,012755.03

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