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Boron trifluoride diethyl etherate, 98+%, Thermo Scientific Chemicals

Product Code. 11432338
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Quantity:
100 mL
500 mL
1000 mL

Boron trifluoride diethyl etherate is used as a Lewis acid catalyst in Mukaiyama aldol addition, alkylation, acetylation, isomerization, dehydrations and condensation reactions. It is involved in the prepattion of polyethers in polymerization reactions. As a catalyst, it is used in the preparation of cyclopentyl- and cycloheptyl[b]indoles and other diborane. It is also used in sensitive neutron detectors in ionization chambers as well as monitoring radiation levels in earth’s atmosphere.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Boron trifluoride diethyl etherate is used as a Lewis acid catalyst in Mukaiyama aldol addition, alkylation, acetylation, isomerization, dehydrations and condensation reactions. It is involved in the prepattion of polyethers in polymerization reactions. As a catalyst, it is used in the preparation of cyclopentyl- and cycloheptyl[b]indoles and other diborane. It is also used in sensitive neutron detectors in ionization chambers as well as monitoring radiation levels in earth’s atmosphere.

Solubility
Miscible with ether and alcohol.

Notes
Moisture sensitive. Store in cool place. Recommended to use under inet atomosphere. Incompatible with metals, acids, bases, alcohols, alkali metals, oxidizing agents and water. Reacts violently with water.
TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 109-63-7
Molecular Formula C4H10BF3O
Molecular Weight (g/mol) 141.93
MDL Number MFCD00013194
InChI Key KZMGYPLQYOPHEL-UHFFFAOYSA-N
Synonym Boron trifluoride etherate; Boron fluoride-ether
PubChem CID 8000
IUPAC Name ethoxyethane;trifluoroborane
SMILES FB(F)F.CCOCC

Specifications

Melting Point -60°C
Density 1.13
Boiling Point 125°C to 126°C
Flash Point 47°C (116°F)
Odor Acrid
Linear Formula BF3€O(CH2CH3)2
Refractive Index 1.344
Quantity 1000 mL
UN Number UN2604
Beilstein 3909607
Sensitivity Moisture sensitive
Merck Index 14,1350
Solubility Information Miscible with ether and alcohol.
Formula Weight 141.93
Percent Purity ≥98%
Chemical Name or Material Boron trifluoride diethyl etherate
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Product Identifier
  • Boron trifluoride diethyl etherate
Signal Word
  • Danger
Hazard Category
  • Acute toxicity Category 4
  • Serious eye damage/eye irritation Category 1
  • Flammable liquid Category 3
  • Skin corrosion/irritation Category 1 B
  • Specific target organ toxicity Category 1
Hazard Statement
  • H226-Flammable liquid and vapour.
  • H314-Causes severe skin burns and eye damage.
  • H318-Causes serious eye damage.
  • H332-Harmful if inhaled.
  • H372-Causes damage to organs.
Precautionary Statement
  • P210-Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
  • P280-Wear protective gloves/protective clothing/eye protection/face protection.
  • P303+P361+P353-IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.
  • P304+P340-IF INHALED: Remove person to fresh air and keep comfortable for breathing.
  • P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
  • P310-Immediately call a POISON CENTER/doctor/.
Supplemental information
  • MIXTURE LIST-Contains : Boron trifluoride-diethyl etherate

RUO – Research Use Only

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