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Bismuth(III) chloride, 97+% (dry wt.), may cont. up to 3% water, Thermo Scientific Chemicals Product Code.: 11458763
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Bismuth(III) chloride, 97+% (dry wt.), may cont. up to 3% water, Thermo Scientific Chemicals

Product Code. 11458763
25 g
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25 g
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500 g
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Product Code. 11458763

Brand: Thermo Scientific Alfa Aesar A10510.14

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Description

Bismuth(III) chloride is used as a catalyst in organic synthesis and to prepare other bismuth salts. It is used as a starting material for the preparation of bismuthoxychloride upon hydrolysis. It is an oxidizing agent to prepare metallic bismuth by reducing agent. Further, it catalyzes the Michael reaction and the Mukaiyama-aldol reaction. In addition to this, it is a Lewis acid.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Bismuth(III) chloride is used as a catalyst in organic synthesis and to prepare other bismuth salts. It is used as a starting material for the preparation of bismuthoxychloride upon hydrolysis. It is an oxidizing agent to prepare metallic bismuth by reducing agent. Further, it catalyzes the Michael reaction and the Mukaiyama-aldol reaction. In addition to this, it is a Lewis acid.

Solubility
Soluble in hydrochloric acid, nitric acid, diethyl ether, ethyl acetate and acetone. Insoluble in alcohol.

Notes
Hygroscopic. Incompatible with strong oxidizing agents.
TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 7787-60-2
Molecular Formula BiCl3
Molecular Weight (g/mol) 315.33
MDL Number MFCD00003461
InChI Key JHXKRIRFYBPWGE-UHFFFAOYSA-K
Synonym bismuth trichloride, bismuth chloride, trichlorobismuthine, trichlorobismuth, bismuth iii chloride, bismuthine, trichloro, trichlorobismute, bismuth lll chlorideShow MoreShow Less
PubChem CID 24591
IUPAC Name trichlorobismuthane
SMILES Cl[Bi](Cl)Cl

Specifications

Boiling Point ∼430°C (sublimation)
Melting Point 230°C to 232°C
Quantity 25 g
UN Number UN3260
Merck Index 14,1262
Solubility Information Soluble in hydrochloric acid,nitric acid,diethyl ether,ethyl acetate and acetone. Insoluble in alcohol.
Formula Weight 315.34
Percent Purity 98%
Concentration or Composition (by Analyte or Components) May contain up to 3% water
Odor Irritating
Sensitivity Moisture sensitive
Density 4.75
Assay (dry wt.)
Chemical Name or Material Bismuth (III) chloride
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5 results found
Lot Number Certificate Type Date Catalog Number
Lot Number10242638 Certificate TypeCertificate of Analysis Date03/08/2022 Catalog NumberA10510.14,A10510.36,A10510.22
Lot Number10144011 Certificate TypeCertificate of Analysis Date22/11/2021 Catalog NumberA10510.14,A10510.36,A10510.22
Lot Number10231332 Certificate TypeCertificate of Analysis Date22/11/2021 Catalog NumberA10510.14,A10510.36,A10510.22
Lot Number10176204 Certificate TypeCertificate of Analysis Date22/11/2021 Catalog NumberA10510.14,A10510.36,A10510.22
Lot Number10185084 Certificate TypeCertificate of Analysis Date22/11/2021 Catalog NumberA10510.14,A10510.36,A10510.22

Safety and Handling

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Product Identifier
  • Bismuth(III) chloride
 Signal Word
  • Danger
 Hazard Category
  • Skin corrosion/irritation Category 1 B
 Hazard Statement
  • H314-Causes severe skin burns and eye damage.
 Precautionary Statement
  • P260-Do not breathe dust/fume/gas/mist/vapours/spray.
  • P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
  • P303+P361+P353-IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.
  • P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
  • P405-Store locked up.
  • P501-Dispose of contents/container to .
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RUO – Research Use Only

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