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1,5-Cyclooctadiene(pyridine)(tricyclohexylphosphine)iridium(I) hexafluorophosphate, 99%, Thermo Scientific Chemicals
Description
1,5-Cyclooctadiene(pyridine)(tricyclohexylphosphine)iridium(I) hexafluorophosphate is used as a catalyst for hydrogenation of mono-, di-, tri-, and tetra-substituted substrates and the isomerization and hydroboration of alkenes. It is also used in isotope exchange reactions, especially the direct exchange of a hydrogen atom with its isotopes deuterium and tritium. Carbonyl groups are also known to direct the hydrogenation by the Crabtree catalyst is highly regioselective.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Specifications
Specifications
| CAS | 64536-78-3 |
| Melting Point | 175°C (decomposition) |
| Molecular Formula | C31H50F6IrNP2 |
| MDL Number | MFCD00075097 |
| Quantity | 250 mg |
| Sensitivity | Moisture sensitive |
| Synonym | crabtree's catalyst, unii-816rs2nbpn, 816rs2nbpn, 1,5-cyclooctadiene pyridine tricyclohexylphosphine iridium hexafluorophosphate, iridium i hexafluorophosphate, 1,5-cyclooctadiene pyridine tricyclohexylphosphine iridium i hexafluorophosphate, tricyclohexylphosphine 1,5-cyclooctadiene pyridine iridium i hexafluorophosphate, felkin-crabtree catalyst, crabtree's catalyst mi, crabtree's catalyst hexafluorophosphate |
| Solubility Information | Slightly soluble in acetone,dichloromethane,ethanol and diethyl ether; Insoluble in water. |
| InChI Key | UJXHUUQZACSUOG-KJWGIZLLSA-N |
| SMILES | [Ir+].C1=CC=NC=C1.F[P-](F)(F)(F)(F)F.C1C\C=C/CC\C=C/1.C1CCC(CC1)P(C1CCCCC1)C1CCCCC1 |
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RUO – Research Use Only